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Comparisons of the Adsorption Equilibrium of Benzene Derivatives in Reversed-Phase Liquid Chromatography

datacite.subject.fosEngenharia e Tecnologia::Engenharia Químicapt_PT
dc.contributor.advisorMota, José
dc.contributor.advisorSeidel-Morgenstern, Andreas
dc.contributor.advisorLee, Ju
dc.contributor.authorSantos, Tiago Pereira dos
dc.date.accessioned2017-05-26T09:15:47Z
dc.date.available2017-05-26T09:15:47Z
dc.date.issued2016-09
dc.date.submitted2017-05
dc.description.abstractThe isotherm behaviour of three benzene derivatives, Valerophenone (VPhn), Butyl Benzoate (BBzt) and tert-butylbenzene (tBBz), as well as two binary mixtures VPhn+tBBz and BBzt+tBBz were studied. To try to describe to explain the isotherm data, the multilayer multi-component model was used, a model recently developed by a research group led by Prof. Andreas Seidel-Morgenstern in the Max Planck Institut for Dynamics of Complex Technical Systems (MPI). The main goal of this work is to obtain experimental validation to this model, which until now only existed in paper. The results showed that this model can describe well the isotherm data for both single and multi component systems. Since multi component experiments consume lots of time and resources, crosschecks between the fitted parameters of single and multi components were performed to see if single parameters could describe well the multi component isotherms. The results show that the cross check is not bad, although it’s always needed some mixture data. Some further work can be done to determine the minimum amount of multi-component data that gives a good description of the mixtures’ isotherm behaviours.pt_PT
dc.identifier.urihttp://hdl.handle.net/10362/20781
dc.language.isoengpt_PT
dc.titleComparisons of the Adsorption Equilibrium of Benzene Derivatives in Reversed-Phase Liquid Chromatographypt_PT
dc.typemaster thesis
dspace.entity.typePublication
rcaap.rightsopenAccesspt_PT
rcaap.typemasterThesispt_PT
thesis.degree.nameMaster of Science in Chemical and Biochemical Engineeringpt_PT

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