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Recent advances in the manipulation of circularly polarised light with cellulose nanocrystal films

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Significant advances have been made to control the iridescence and the selective reflection of left circularly polarised (LCP) light, and transmission of right circularly polarised (RCP) light of solid films prepared from cellulose nanocrystals (CNCs). However the manipulation of the photonic properties of the CNCs films, which reflect both RCP and LCP light is less investigated. Solid films prepare from natural sources as CNCs have advantageous characteristics that are absent in other synthetic structures, such as wide availability and renewability. Here we review and compare recent research activity involving the production and characterization of photonic band gap structures resulting from an anisotropic layer inserted between two cholesteric layers with different helical pitches but the same handedness. We make connections between systems existing in Nature and synthetic ones with the hope of advancing in the production and manipulation of CNCs-based photonic structures.

Descrição

This work is funded by FEDER funds through the COMPETE 2020 Program, National Funds through FCT - Portuguese Foundation for Science and Technology and POR Lisboa2020 , under the projects with references POCI- 01-0145-FEDER-007688 (Reference UID/CTM/50025), UID/BIA/00329/2013, PTDC/CTM-BIO/6178/2014, M-ERA-NET2/0007/2016 (CellColor) and PTDC/CTM-REF/30529/2017. S.N. Fernandes and L.F. Lopes acknowledge the Minister of Science, Technology and Higher Education for National Funds , European Social Funds and FCT for fellowships number SFRH/BDP/78430/2011 and SFRH/BPD/84478/2012 , respectively. This work was supported by the Histology and Comparative Pathology laboratory [Electron Microscopy service] of the Instituto de Medicina Molecular João Lobo Antunes, specifically Andreia Pinto for her kind support. We would like to thank Carlos Silva for providing the C. chrysina specimen. The C. aurata specimen observed was provided by the Insect Collection of the National Museum of Natural History and Science, University of Lisbo

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Bio-inspired materials Cellulose nanocrystals Circularly polarised light Iridescence Liquid crystals Photonics General Materials Science

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