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Polyamine ligand-mediated self-assembly of gold and silver nanoparticles into chainlike structures in aqueous solution

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Fernandez_Lodeiro_et_al_2013_ChemistryOpen.pdf3.46 MBAdobe PDF Ver/Abrir

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1D Nanochain formation: The binding ability of a polyamine molecular linker (L)2- bearing different functional groups, which favors the self-assembling of silver (AgNPs) and gold nano-particles (AuNPs) into 1D nanochains in aqueous solution was explored. UV/Vis spectrophotometry and TEM were used to determine time-dependent structural changes associated with these 1D structure formations. Sensing of Hg2+ using AgNPs@ (L) 2- and AuNPs@ (L)2- assemblies was also carried out in aqueous solution. © 2013 The Authors. Published by Wiley-VCH Verlag GmbH& Co. KGaA, Weinheim.

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We are grateful to the Scientific Association ProteoMass (Portugal) for financial support. C.N. thanks Xunta de Galicia (Spain) for her postdoctoral contract (I2C program).

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1D nanochains Gold Mercury Nanoparticles Self-assembly Silver General Chemistry

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