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Reactivity of hypervalent iodine(III) reagents bearing a benzylamine with sulfenate salts
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Orientador(es)
Resumo(s)
The reactivity of our recently disclosed hypervalent iodine reagents (HIRs) bearing a benzylamine with in situ-generated sulfenate salts was investigated. Under the studied conditions sulfonamides have been obtained in up to 52% yield. This reaction has been extended to a variety of HIRs and sulfenate salts to explore the different reactivity of these new reagents. A plausible mechanism is proposed, suggesting a possible radical pathway.
Descrição
PT2020 Partnership Agreement (POCI-01-0145-FEDER - 007265).
Publisher Copyright:
© 2024 Dedeiras et al.
Palavras-chave
electrophilic amination hypervalent iodine reagents sulfinamide sulfonamide Organic Chemistry