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Ionic Liquid Crystals as Chromogenic Materials

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Ionic liquid crystals (ILCs), a class of soft matter materials whose properties can be tuned by the wise pairing of the cation and anion, have recently emerged as promising candidates for different applications, combining the characteristics of ionic liquids and liquid crystals. Among those potential uses, this review aims to cover chromogenic ILCs. In this context, examples of photo-, electro- and thermochromism based on ILCs are provided. Furthermore, thermotropic and lyotropic ionic liquid crystals are also summarised, including the most common chemical and phase structures, as well as the advantages of confining these materials. This manuscript also comprises the following main experimental techniques used to characterise ILCs: Differential Scanning Calorimetry (DSC), Polarised Optical Microscopy (POM) and X-Ray Powder Diffraction (XRD). Chromogenic ILCs can be interesting smart materials for energy and health purposes.

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The authors also thank the COST Action PhoBioS (CA21159), PRR InsectERA (n\u00BA C644917393-00000032) and PRR BioEquip (n\u00BA C645808870-00000067). © 2024 by the authors. Licensee MDPI, Basel, Switzerland.

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chromogenic materials electrochromism ionic liquid crystals photochromism thermochromism General Materials Science Condensed Matter Physics

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