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Synergistic effects of Monel 400 filler wire in gas metal arc welding of CoCrFeMnNi high entropy alloy
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Resumo(s)
Weldability plays a crucial role in the journey of high entropy alloys towards their engineering applications. In this study, gas metal arc welding was performed to join an as-rolled CoCrFeMnNi high entropy alloy using Monel 400 as the filler wire. The present research findings demonstrate a favorable metallurgical chemical reaction between the Monel 400 filler and the CoCrFeMnNi high entropy alloy, resulting in compositional mixing within the fusion zone that promotes a solid-solution strengthening effect, counteracting the typical low hardness associated to the fusion zone of these alloys. The weld thermal cycle induced multiple microstructure changes across the joint, including variations in the grain size, existing phases and local texture. The grain size was seen to increase from the base material toward the fusion zone. An FCC matrix and finely sparse Cr-Mn-based oxides existed in both base material and heat affected zone, while in the fusion zone new FCC phases and carbides were formed upon the mixing of the Monel 400 filler. The role of the filler material on the fusion zone microstructure evolution was rationalized using thermodynamic calculations. Texture shifted from a γ-fiber (in the base material) to a strong cubic texture in the fusion zone. Digital image correlation during tensile testing to fracture coupled with microhardness mapping revealed that, stemming from the process-induced microstructure changes, the micro and macromechanical response differed significantly from the original base material. This study successfully established a correlation between the impact of the process on the developed microstructural features and the resultant mechanical behavior, effectively assessing the processing-microstructure-properties relationships towards an improved understanding of the physical metallurgy associated to these advanced engineering alloys. In conclusion, this work provides an important theoretical framework and practical guidance for optimizing the engineering applications of high entropy alloys.
Descrição
Funding Information: JS and JPO acknowledge Fundação para a Ciência e a Tecnologia (FCT - MCTES) for its financial support via the project UID/00667/2020 (UNIDEMI). JPO acknowledges the funding of CENIMAT/i3N by national funds through the FCT-Fundação para a Ciência e a Tecnologia, I.P., within the scope of Multiannual Financing of R&D Units, reference UIDB/50025/2020-2023. JS acknowledges the China Scholarship Council for funding the Ph.D. grant (CSC NO. 201808320394). This work was supported by the National Research Foundation of Korea (NRF) with a grant funded by the Korea government (MSIP) (NRF-2021R1A2C3006662). The authors acknowledge DESY (Hamburg, Germany), a member of the Helmholtz Association HGF, for the provision of experimental facilities. Beamtime was allocated for proposal I-20210899 EC. The research leading to this result has been supported by the project CALIPSOplus under the Grant Agreement 730872 from the EU Framework Programme for Research and Innovation HORIZON 2020. Funding Information: JS and JPO acknowledge Funda\u00E7\u00E3o para a Ci\u00EAncia e a Tecnologia (FCT - MCTES) for its financial support via the project UID/00667/2020 ( UNIDEMI ). JPO acknowledges the funding of CENIMAT/ i3N by national funds through the FCT- Funda\u00E7\u00E3o para a Ci\u00EAncia e a Tecnologia , I.P., within the scope of Multiannual Financing of R&D Units, reference UIDB/50025/2020-2023. JS acknowledges the China Scholarship Council for funding the Ph.D. grant ( CSC NO . 201808320394 ). This work was supported by the National Research Foundation of Korea (NRF) with a grant funded by the Korea government (MSIP) (NRF-2021R1A2C3006662). The authors acknowledge DESY (Hamburg, Germany), a member of the Helmholtz Association HGF, for the provision of experimental facilities. Beamtime was allocated for proposal I-20210899 EC . The research leading to this result has been supported by the project CALIPSOplus under the Grant Agreement 730872 from the EU Framework Programme for Research and Innovation HORIZON 2020 . Publisher Copyright: © 2024 The Authors
Palavras-chave
CoCrFeMnNi high entropy alloy Digital image correlation Gas metal arc welding Mechanical testing Monel NiCu-7 filler wire Thermodynamic calculations General Materials Science Mechanics of Materials Mechanical Engineering