Opportunities from Metal Organic Frameworks to Develop Porous Carbons Catalysts Involved in Fine Chemical Synthesis

Pérez-Mayoral, Elena; Godino-Ojer, Marina; Matos, Inês; Bernardo, Maria

http://hdl.handle.net/10362/154567

Utilize este identificador para referenciar este registo.

Nome:	Descrição:	Tamanho:	Formato:
Opportunities_from_Metal.pdf		29.34 MB	Adobe PDF	Ver/Abrir

Contacte-nos

Autores

Resumo(s)

In the last decade, MOFs have been proposed as precursors of functional porous carbons with enhanced catalytic performances by comparison with other traditional carbonaceous catalysts. This area is rapidly growing mainly because of the great structural diversity of MOFs offering almost infinite possibilities. MOFs can be considered as ideal platforms to prepare porous carbons with highly dispersed metallic species or even single-metal atoms under strictly controlled thermal conditions. This review briefly summarizes synthetic strategies to prepare MOFs and MOF-derived porous carbons. The main focus relies on the application of the MOF-derived porous carbons to fine chemical synthesis. Among the most explored reactions, the oxidation and reduction reactions are highlighted, although some examples of coupling and multicomponent reactions are also presented. However, the application of this type of catalyst in the green synthesis of biologically active heterocyclic compounds through cascade reactions is still a challenge.

Descrição

Funding Information: This work has been supported by Project ref. PID2021-126579OB-C32 from MCIN/AEI/10.13039/501100011033 and Project ref. UFV2023-38 from Universidad Francisco de Vitoria de Madrid. Maria Bernardo thanks FCT (Fundação para a Ciência e Tecnologia) for funding through program DL 57/2016—Norma transitória. Publisher Copyright: © 2023 by the authors.