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Orientador(es)
Resumo(s)
A porous high entropy alloy (HEA) coating was prepared on a steel surface by vacuum sintering. The coating was then used as a transition layer during dissimilar laser joining of Al to steel. Compared with the uncoated laser joints, the liquid alloy spread and infiltrated into the porous structure, the contact angle of the weld reduced from 65.8° to 56.7°, and the brazed width increased from 5.1 mm to 5.9 mm, which improved the wettability and spreadability of the molten filler wire on the substrate. In the case of the uncoated steel, the fusion zone/steel interfacial microstructure consisted of laminated Al7·2Fe1·8Si and Fe(Al,Si)3, while it changed to a composite-like structure containing a soft HEA skeleton and hard IMCs which included Al7·2Fe1·8Si, Al3Ni, and (Al,Si)2Cr. In addition, due to the sluggish diffusion effect of HEAs, a layer of gradient nanocrystalline composed of Al7·2Fe1·8Si was generated, which significantly strengthened the dissimilar laser joints with improvements in both the fracture load (∼26.5%) and the displacement (∼101.8%). The fracture mode changed from brittle to ductile failure when the porous HEA coating was applied, with fracture propagating through the HEA skeleton. This work provides a novel solution for the strengthening of hard-to-join dissimilar combinations.
Descrição
Publisher Copyright: © 2023 The Authors This work was supported by the National Natural Science Foundation of China (No. 52275155) and Class III Peak Discipline of Shanghai-Materials Science and Engineering. JPO acknowledges funding by national funds from FCT-Fundacao para a Ciencia e a Tecnologia, I.P., in the scope of the projects LA/P/0037/2020, UIDP/50025/2020 and UIDB/50025/2020 of the Associate Laboratory Institute of Nanostructures, Nano-modelling and Nanofabrication-i3N.
Palavras-chave
High entropy alloy Interfacial microstructure Laser welding Mechanical properties Porous coating Ceramics and Composites Biomaterials Surfaces, Coatings and Films Metals and Alloys
