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2,2'-(2,2'-oxybis(ethane-2,1-diyl)bis(oxy))bis(N-(2,2'-bithiophen-5-ylmethylene)aniline)

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A new flexible fluorescent compound L derived from 1,5-bis(2-aminophenoxy)-3-oxapentane (A) has been synthesized by classical Schiff-base reaction between (A) and 2,2 ́-bithiophene carbaldehyde (B). The same synthesis was reproduced by a green methodology using an ultrasonication reaction in a classical sonication bath. The structure of the new compound was confirmed by elemental analysis, IR, 1H-NMR, MALDI-TOF-MS and EI-MS-spectra, UV-vis and fluorescence emission spectroscopy.

Descrição

We would like to thank Xunta de Galiza (Spain) for project 09CSA043383PR and the University of Vigo, Vicou for projects INOU UVIGO/VICOU/K914-122P64702/2009 and UVIGO/VICOU/K912-122P64702/2009. Thanks to the FCT-MCTES/FEDER (Portugal) through national project PDTC/QUI/66250/2006. C.L. and J.L. thank Xunta de Galicia for the Isidro Parga Pondal Research Program.

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2,2'-bithiophene Fluorescence chemosensors Imine compounds Biochemistry Physical and Theoretical Chemistry Organic Chemistry

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