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Electrical ageing studies of polymeric insulation for power cables (estudo do envelhecimento eléctrico do isolante polimérico de cabos eléctricos

dc.contributor.advisorMendes, Marat
dc.contributor.advisorGupta, Dilip Das
dc.contributor.authorLanca, M C
dc.date.accessioned2011-01-05T12:29:22Z
dc.date.available2011-01-05T12:29:22Z
dc.date.issued2002
dc.descriptionDissertação apresentada para obtenção do Grau de Doutor em Engenharia Física - Física Aplicada pela Universidade Nova de Lisboa, Faculdade de Ciências e Tecnologiaen_US
dc.description.abstractPolymers have been widely used as electrical insulators in power cables. Polyethylene, initially low density and more recently crosslinked, are one of the more commonly used insulators in medium and high voltage power cables. They suffer electrical ageing in different forms, such as water treeing, electrical treeing and finally dielectric breakdown. The last one leading to costly cable failure. Many research works have been developed on this subject despite of the progress made up to now, results are still sometimes contradictory and difficult to reproduce. Any new insight into this problem is a step further in preventing failure of the cables and increasing their useful lifetime. The aim of this thesis was to relate ageing in two different aspects of electrical ageing: localised damage and changes in bulk properties of the polyethylene. For this different experimental techniques were used. Localised damage was water treeing and breakdown channels since no electrical trees were observed. The methods used for this study were FTIR,estimation of fractal dimension of water trees and statistics of dielectric breakdown. The changes of electric and dielectric bulk properties were accessed using mostly DRS, FTSDC and PEA. From the FTIR results it was possible to find oxidation products (mainly ketones and carboxylate ions) and chain scission. The values estimated for fractal dimension point to the same underlying microscopic mechanism for water treeing (at least for samples aged at different frequency and temperature). Breakdown statistics point to the important role of manufacture and processing of the insulator, since early breakdown is mostly dependent on defects resulting from these processes. A correlation between DRS, FTSDC and PEA shows the role played by space charge and trapping on ageing for longer times. The two different aspects (localised and bulk) are difficult to correlate because the first one has a stochastic behaviour. However the presence of space charge found in bulk studies can be regard as one of the initiator factors for localised damage.en_US
dc.description.sponsorshipFundação Calouste Gulbenkianen_US
dc.identifier.urihttp://hdl.handle.net/10362/4769
dc.language.isoeng
dc.publisherFaculdade de Ciências e Tecnologiaen_US
dc.titleElectrical ageing studies of polymeric insulation for power cables (estudo do envelhecimento eléctrico do isolante polimérico de cabos eléctricosen_US
dc.typedoctoral thesis
dspace.entity.typePublication
my.embargo.termsnullen_US
rcaap.rightsopenAccessen_US
rcaap.typedoctoralThesisen_US

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