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UV-cured self-healing gel polymer electrolyte toward safer room temperature lithium metal batteries

2022-11-20Artigo científico Acesso aberto
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dc.contributor.authorSiccardi, Simone
dc.contributor.authorAmici, Julia
dc.contributor.authorColombi, Samuele
dc.contributor.authorCarvalho, Jose Tiago
dc.contributor.authorVersaci, Daniele
dc.contributor.authorQuartarone, Eliana
dc.contributor.authorPereira, Luis
dc.contributor.authorBella, Federico
dc.contributor.authorFrancia, Carlotta
dc.contributor.authorBodoardo, Silvia
dc.contributor.institutionDCM - Departamento de Ciência dos Materiais
dc.contributor.institutionCENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)
dc.contributor.institutionUNINOVA-Instituto de Desenvolvimento de Novas Tecnologias
dc.contributor.pblInternational Society of Electrochemistry (ISE) | Elsevier
dc.date.accessioned2022-12-19T22:13:31Z
dc.date.available2022-12-19T22:13:31Z
dc.date.issued2022-11-20
dc.description
dc.description.abstractSolid polymer electrolytes are considered a useful solution for improving the safety of lithium metal batteries. However, these macromolecular systems show low ionic conductivity and suffer from limited cyclability at room temperature. In this work we propose the UV-induced, solvent-free radical copolymerization of poly(ethylene glycol) methyl ether methacrylate (PEGMEM, MW 500) and 2-(3-(6-methyl-4-oxo-1,4-dihydropyrimidin-2-yl)ureido)ethyl methacrylate (UpyMa) in the presence of poly(ethylene glycol) diacrylate (PEGDA, MW 575), used as crosslinker. The polymers, after activation in small amount of liquid electrolyte, show high thermal resistance, good lithium-ion conductivity and wide electrochemical window. Moreover, thanks to the quadruple hydrogen bond interaction of UpyMa dimer, the polymers show good self-healing properties both at 50 °C and room temperature. Such prepared polymers possess excellent interfacial stability and allow for stable lithium plating and stripping at room temperature. Last but not least, cycling tests against LFP cathode showed a fair and stable discharge capacity at 0.2C with 80% of capacity retention after 300 cycles. Most importantly, after severely mechanically damaging the electrolyte, it showed great recovery of the electrochemical properties, with a restored capacity of 115 mAh g−1 at 0.2C and room temperature. This work highlights a promising strategy for safer room-temperature self-healing quasi solid-state lithium metal batteries.en
dc.description.versionpublishersversion
dc.description.versionpublished
dc.format.extent11
dc.format.extent10533423
dc.identifier.doi10.1016/j.electacta.2022.141265
dc.identifier.issn0013-4686
dc.identifier.otherPURE: 48273601
dc.identifier.otherPURE UUID: 642f63d5-beff-4590-acb8-08962bd75c44
dc.identifier.otherWOS: 000870474300005
dc.identifier.otherScopus: 85138834153
dc.identifier.urihttp://hdl.handle.net/10362/146406
dc.language.isoeng
dc.peerreviewedyes
dc.relationinfo:eu-repo/grantAgreement/FCT/OE/SFRH%2FBD%2F139225%2F2018/PT
dc.relationSustainable functionalized fiber-based structures for application in electronic and electrochemical systems
dc.relationinfo:eu-repo/grantAgreement/FCT/3599-PPCDT/PTDC%2FCTM-CTM%2F4653%2F2021/PT
dc.relationSYmbiosis for eNERGY harversting concepts for smart platforms on foils
dc.subjectRoom temperature
dc.subjectDimers
dc.subjectElectric discharges
dc.subjectEthylene glycol
dc.subjectFree radicals
dc.subjectHydrogen bonds
dc.subjectLithium-ion batteries
dc.subjectOrganic solvents
dc.subjectPolyelectrolytes
dc.subjectPolyethylene glycols
dc.subjectPolyols
dc.subjectSolid electrolytes
dc.subjectCyclability
dc.subjectFree radical copolymerization
dc.subjectGel polymer electrolytes
dc.subjectLithium metals
dc.subjectMacromolecular
dc.subjectsystems
dc.subjectSelf-healing
dc.subjectSolid polymer electrolytes
dc.subjectSolvent free
dc.subjectUV cured
dc.subjectUV induced
dc.subjectSDG 7 - Affordable and Clean Energy
dc.titleUV-cured self-healing gel polymer electrolyte toward safer room temperature lithium metal batteriesen
dc.typejournal article
degois.publication.titleElectrochimica Acta
degois.publication.volume433
dspace.entity.typePublication
oaire.awardNumberSFRH/BD/139225/2018
oaire.awardNumberPTDC/NAN-MAT/32558/2017
oaire.awardNumberPTDC/CTM-CTM/4653/2021
oaire.awardNumber952169
oaire.awardTitleSustainable functionalized fiber-based structures for application in electronic and electrochemical systems
oaire.awardTitleSYmbiosis for eNERGY harversting concepts for smart platforms on foils
oaire.awardURIinfo:eu-repo/grantAgreement/FCT//SFRH%2FBD%2F139225%2F2018/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/3599-PPCDT/PTDC%2FNAN-MAT%2F32558%2F2017/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/3599-PPCDT/PTDC%2FCTM-CTM%2F4653%2F2021/PT
oaire.awardURIinfo:eu-repo/grantAgreement/EC/H2020/952169/EU
oaire.fundingStream3599-PPCDT
oaire.fundingStream3599-PPCDT
oaire.fundingStreamH2020
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100008530
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameEuropean Commission
rcaap.rightsopenAccess
relation.isProjectOfPublication0f4cf804-d824-4e04-b627-09b84dc7e9a8
relation.isProjectOfPublicationb47e7103-e1d4-4362-8f3f-9df7717317b1
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relation.isProjectOfPublicationcb227cbb-ddcb-45fb-adb9-1322971370cf
relation.isProjectOfPublication.latestForDiscovery4f5e25f1-4a1b-42b6-b899-f66d9e94027d

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