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Triazaphosphaadamantane-functionalized terpyridine metal complexes

2022-12-01Artigo científico Acesso aberto
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dc.contributor.authorLibrando, Ivy L.
dc.contributor.authorPaul, Anup
dc.contributor.authorMahmoud, Abdallah G.
dc.contributor.authorGurbanov, Atash V.
dc.contributor.authorCarabineiro, Sónia A. C.
dc.contributor.authorSilva, M. Fátima C. Guedes da
dc.contributor.authorGeraldes, Carlos F. G. C.
dc.contributor.authorPombeiro, Armando J. L.
dc.contributor.institutionLAQV@REQUIMTE
dc.contributor.institutionDQ - Departamento de Química
dc.contributor.pblRSC - Royal Society of Chemistry
dc.date.accessioned2023-01-04T22:17:20Z
dc.date.available2023-01-04T22:17:20Z
dc.date.issued2022-12-01
dc.descriptionThe work was also funded by national funds through FCT, under the Scientific Employment Stimulus-Institutional Call (CEEC-INST/00102/2018). We also acknowledge the Associate Laboratory for Green Chemistry – LAQV financed by national funds from FCT/MCTES (UIDP/5006/2020). A. P. is grateful to FCT and Instituto Superior Técnico (IST), Portugal through DL/57/2017 (Contract no. IST-ID/197/2019). AGM is grateful to Associação do Instituto Superior Técnico para Investigação e Desenvolvimento for his post-doctoral fellowship through grant no. BL133/2021-IST-ID. This publication is also supported by the RUDN University Strategic Academic Leadership Program (recipient AJLP, preparation). A. V. G. thanks FCT, Instituto Superior Técnico (L 57/2017 and CEEC Institutional 2018 Programs, Contract no: IST-ID/110/2018) and Baku State University for financial support. The authors also acknowledge the Portuguese NMR Network (IST-UL Centre) for access to the NMR facility. CFGCG thanks the FCT for funding , also co-founded by FEDER/ COMPETE 2020-EU. The authors are also thankful to Benjoe Rey B. Visayas (University of Massachusetts Dartmouth) for the help with the graphics.
dc.description.abstractIn accordance with UN's Sustainable Development Goal (UN's SDG) 12 which encompasses the sustainable use of chemical products and a sound circular economy, this work is focused on the synthesis of Co(II), Ni(II) and Mn(II) complexes bearing combined 1,3,5-triaza-7-phosphaadamantane and benzyl terpyridine core moieties (PTA–Bztpy) as ligand, followed by their evaluation as catalysts for the microwave-assisted cyclohexane oxidation using tert-butyl hydroperoxide (TBHP) as oxidant. The most active catalyst, with a manganese metal center, was heterogenized on six different carbon materials. The results disclosed the influence of several reaction parameters, such as catalyst loading, temperature, reaction time and solvent, on the catalytic activity and selectivity of the homogeneous and carbon-supported catalysts. Recyclability of the carbon-supported catalyst allowed facile separations, recovery and reuse for five consecutive cycles.en
dc.description.versionpublishersversion
dc.description.versionpublished
dc.format.extent12
dc.format.extent2049925
dc.identifier.doi10.1039/D2SU00017B
dc.identifier.otherPURE: 48174000
dc.identifier.otherPURE UUID: 33970695-e65c-4cbb-9a0f-156fa4f7be29
dc.identifier.otherORCID: /0000-0001-9913-4671/work/123988092
dc.identifier.urihttp://hdl.handle.net/10362/146968
dc.identifier.urlhttps://doi.org/10.1039/D2SU00017B
dc.language.isoeng
dc.peerreviewedyes
dc.relationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00100%2F2020/PT
dc.relationCentro de Química Estrutural
dc.relationAssociated Laboratory for Green Chemistry - Clean Technologies and Processes
dc.relationLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
dc.relationLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
dc.relationSynthesis of high added-value Products Using Hybrid Catalysts and microwave irradiation
dc.relationNot Available
dc.relationCoimbra Chemistry Center
dc.relationCoimbra Chemistry Center
dc.relationinfo:eu-repo/grantAgreement/FCT/DL 57%2F2016/dl 57%2F2016%2FCP1364%2FCT0010/PT
dc.relationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00313%2F2020/PT
dc.relationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F00313%2F2020/PT
dc.titleTriazaphosphaadamantane-functionalized terpyridine metal complexesen
dc.title.subtitlecyclohexane oxidation in homogeneous and carbon-supported catalysisen
dc.typejournal article
degois.publication.titleRSC Sustainability
dspace.entity.typePublication
oaire.awardNumberUIDB/00100/2020
oaire.awardNumberUIDB/50006/2020
oaire.awardNumberUIDB/50020/2020
oaire.awardNumberUIDP/50020/2020
oaire.awardNumberPD/BD/135555/2018
oaire.awardNumberdl 57/2016/CP1364/CT0010
oaire.awardNumberUIDB/00313/2020
oaire.awardNumberUIDP/00313/2020
oaire.awardTitleCentro de Química Estrutural
oaire.awardTitleAssociated Laboratory for Green Chemistry - Clean Technologies and Processes
oaire.awardTitleLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
oaire.awardTitleLaboratory of Separation and Reaction Engineering - Laboratory of Catalysis and Materials
oaire.awardTitleSynthesis of high added-value Products Using Hybrid Catalysts and microwave irradiation
oaire.awardTitleNot Available
oaire.awardTitleCoimbra Chemistry Center
oaire.awardTitleCoimbra Chemistry Center
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00100%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50006%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50020%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F50020%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/OE/PD%2FBD%2F135555%2F2018/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/DL 57%2F2016/dl 57%2F2016%2FCP1364%2FCT0010/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F00313%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F00313%2F2020/PT
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStreamOE
oaire.fundingStreamDL 57/2016
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStream6817 - DCRRNI ID
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