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Electrodialytic lithium extraction from secondary resources

2025-12Artigo científico Acesso aberto
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dc.contributor.authorAlmeida, Joana
dc.contributor.authorGouveia, Joana R.
dc.contributor.authorRibeiro, Inês S.
dc.contributor.authorPires, Carolina
dc.contributor.authorMateus, Eduardo P.
dc.contributor.authorRibeiro, Alexandra B.
dc.contributor.institutionCENSE - Centro de Investigação em Ambiente e Sustentabilidade
dc.contributor.pblElsevier BV
dc.date.accessioned2025-10-27T22:04:08Z
dc.date.available2025-10-27T22:04:08Z
dc.date.issued2025-12
dc.descriptionFunding Information: The work has received funding from the Horizon Europe program, grant agreement number 101069789: project RELiEF – Recycling of Lithium from secondary raw materials and further. CENSE is supported by national funding through FCT – Fundação para a Ciência e a Tecnologia, I.P., in the scope of the projects UIDB/04085/2020 (DOI 10.54499/UIDB/04085/2020) and UIDP/04085/2020 (DOI 10.54499/UIDP/04085/2020). CHANGE is funded by FCT under LA/P/0121/2020 (DOI 10.54499/LA/P/0121/2020). The authors also acknowledge FCT for its financial support via the project UIDB/50022/2020 (LAETA Base Funding). The research was also supported by national funds through FCT/MCTES (PIDDAC): LEPABE, UIDB/00511/2020 (DOI: 10.54499/UIDB/00511/2020), UIDP/00511/2020 (DOI: 10.54499/UIDP/00511/2020) and ALiCE, LA/P/0045/2020 (DOI: 10.54499/LA/P/0045/2020). This study was anchored by the RESOLUTION LAB, an infrastructure at NOVA School of Science and Technology. Disclaimer: Funded by the European Union. Publisher Copyright: © 2025 The Authors
dc.description.abstractIn transportation, large-scale electrification, particularly through lithium-ion batteries, is expected to drive significant emissions reductions while simultaneously increasing global lithium demand. However, the limited availability of lithium, compounded by geopolitical constraints, poses risks to the energy transition, namely in the European Union. Adopting circular economy models offers a sustainable approach to increase resource recovery. The present research aims to assess the potential of the electrodialytic process for lithium recovery from wastewater generated during lithium-ion battery recycling and aluminium-lithium alloy dust processing, as well as related environmental and economic impacts. Bench-scale experiments were conducted using two-compartment electrodialytic reactors, operated at 50 mA, 100 mA and 200 mA with a cation-exchange membrane interposed. Tests were performed over 24 h, 48 h and 72 h. Lithium recovery reached 91.54 % from the aluminium-lithium alloy dust and 97.23 % from the wastewater of lithium-ion battery recycling. The cradle-to-gate life cycle assessment resulted in 0.26 kg of CO2 eq/g Li global warming impacts for wastewater of lithium-ion battery recycling, and 46.40 kg of CO2 eq/g Li for aluminium-lithium alloy dust. Material flow cost accounting showed lower recovery costs for wastewater (0.36 €/g Li versus 129.26 €/g Li). Energy consumption in the reactor is the primary hotspot, where optimizing energy and time efficiency could reduce environmental and economic impacts.en
dc.description.versionpublishersversion
dc.description.versionpublished
dc.format.extent14
dc.format.extent2378557
dc.identifier.doi10.1016/j.scp.2025.102189
dc.identifier.issn2352-5541
dc.identifier.otherPURE: 133204866
dc.identifier.otherPURE UUID: 1f7a0eb4-8805-4be7-a74a-dea1b73198d2
dc.identifier.otherScopus: 105015209239
dc.identifier.otherWOS: 001568229300002
dc.identifier.otherORCID: /0000-0002-5606-3591/work/195350281
dc.identifier.urihttp://hdl.handle.net/10362/189783
dc.identifier.urlhttps://www.scopus.com/pages/publications/105015209239
dc.identifier.urlhttps://www.webofscience.com/wos/woscc/full-record/WOS:001568229300002
dc.language.isoeng
dc.peerreviewedyes
dc.relationinfo:eu-repo/grantAgreement/FCT/Concurso de avaliação no âmbito do Programa Plurianual de Financiamento de Unidades de I&D (2017%2F2018) - Financiamento Base/UIDB%2F04085%2F2020/PT
dc.relationinfo:eu-repo/grantAgreement/FCT/Concurso de avaliação no âmbito do Programa Plurianual de Financiamento de Unidades de I&D (2017%2F2018) - Financiamento Programático/UIDP%2F04085%2F2020/PT
dc.relationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/LA%2FP%2F0121%2F2020/PT
dc.relationCHANGE - Global Change and Sustainability Institute
dc.relationinfo:eu-repo/grantAgreement/FCT/Concurso de avaliação no âmbito do Programa Plurianual de Financiamento de Unidades de I&D (2017%2F2018) - Financiamento Base/UIDB%2F00511%2F2020/PT
dc.relationLaboratory for Process Engineering, Environment, Biotechnology and Energy
dc.relationinfo:eu-repo/grantAgreement/FCT/Concurso para Atribuição do Estatuto e Financiamento de Laboratórios Associados (LA)/LA%2FP%2F0045%2F2020/PT
dc.subjectElectro-based technology
dc.subjectLife cycle assessment
dc.subjectLithium
dc.subjectWaste recovery
dc.subjectEnvironmental Chemistry
dc.subjectPollution
dc.subjectPharmaceutical Science
dc.subjectManagement, Monitoring, Policy and Law
dc.subjectSDG 7 - Affordable and Clean Energy
dc.subjectSDG 8 - Decent Work and Economic Growth
dc.subjectSDG 12 - Responsible Consumption and Production
dc.titleElectrodialytic lithium extraction from secondary resourcesen
dc.title.subtitleTechnical, environmental and economic assessmenten
dc.typejournal article
degois.publication.firstPage1
degois.publication.lastPage14
degois.publication.titleSustainable Chemistry and Pharmacy
degois.publication.volume48
dspace.entity.typePublication
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oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F00511%2F2020/PT
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oaire.fundingStreamConcurso de avaliação no âmbito do Programa Plurianual de Financiamento de Unidades de I&D (2017/2018) - Financiamento Base
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oaire.fundingStream6817 - DCRRNI ID
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oaire.fundingStreamConcurso de avaliação no âmbito do Programa Plurianual de Financiamento de Unidades de I&D (2017/2018) - Financiamento Base
oaire.fundingStream6817 - DCRRNI ID
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