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Advanced Functional Luminescent Metallomesogens

2021-10-27Recensão Acesso aberto
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dc.contributor.authorCuerva, Cristián
dc.contributor.authorCano, Mercedes
dc.contributor.authorLodeiro, Carlos
dc.contributor.institutionLAQV@REQUIMTE
dc.contributor.institutionDQ - Departamento de Química
dc.contributor.pblACS - American Chemical Society
dc.date.accessioned2022-09-26T22:30:38Z
dc.date.available2022-10-28T00:33:22Z
dc.date.embargoedUntil2022-10-27
dc.date.issued2021-10-27
dc.description
dc.description.abstractThe use of liquid crystals for the fabrication of displays incorporated in technological devices (TVs, calculators, screens of eBook's, tablets, watches) demonstrates the relevance that these materials have had in our way of living. However, society evolves, and improved devices are looked for as we create a more efficient and safe technology. In this context, metallomesogens can behave as multifunctional materials because they can combine the fluidic state of the mesophases with properties such as photo and electroluminescence, which offers new exciting possibilities in the field of optoelectronics, energy, environment, and even biomedicine. Herein, it has been established the role of the molecular geometry induced by the metal center in metallomesogens to achieve the self-assembly required in the liquid-crystalline mesophase. Likewise, the effect of the coordination environment in metallomesogens has been further analyzed because of its importance to induce mesomorphism. The structural analysis has been combined with an in-depth discussion of the properties of these materials, including their current and potential future applications. This review will provide a solid background to stimulate the development of novel and attractive metallomesogens that allow designing improved optoelectronic and microelectronic components. Additionally, nanoscience and nanotechnology could be used as a tool to approach the design of nanosystems based on luminescent metallomesogens for use in bioimaging or drug delivery.en
dc.description.versionauthorsversion
dc.description.versionpublished
dc.format.extent45
dc.format.extent8060452
dc.identifier.doi10.1021/acs.chemrev.1c00011
dc.identifier.issn0009-2665
dc.identifier.otherPURE: 45663368
dc.identifier.otherPURE UUID: 2b4c6f02-cab3-4d3d-80bd-4087fe041fc0
dc.identifier.otherScopus: 85113697710
dc.identifier.otherPubMed: 34370446
dc.identifier.otherWOS: 000713054600014
dc.identifier.urihttp://hdl.handle.net/10362/144031
dc.identifier.urlhttps://www.scopus.com/pages/publications/85113697710
dc.language.isoeng
dc.peerreviewedyes
dc.relationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50006%2F2020/PT
dc.relationAssociated Laboratory for Green Chemistry - Clean Technologies and Processes
dc.subjectGeneral Chemistry
dc.titleAdvanced Functional Luminescent Metallomesogensen
dc.title.subtitleThe Key Role of the Metal Centeren
dc.typereview
degois.publication.firstPage12966
degois.publication.issue20
degois.publication.lastPage13010
degois.publication.titleChemical Reviews
degois.publication.volume121
dspace.entity.typePublication
oaire.awardNumberUIDB/50006/2020
oaire.awardTitleAssociated Laboratory for Green Chemistry - Clean Technologies and Processes
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50006%2F2020/PT
oaire.fundingStream6817 - DCRRNI ID
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccess
relation.isProjectOfPublicationadc84c24-ba1d-4bcd-b753-2128ce9a5faa
relation.isProjectOfPublication.latestForDiscoveryadc84c24-ba1d-4bcd-b753-2128ce9a5faa

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