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Determination of Boron Content in Surface Paintings From Historical Stained-Glass Windows

2025-02-03Artigo científico Acesso aberto
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dc.contributor.authorMaestro-Guijarro, Laura
dc.contributor.authorSedano, Mercedes
dc.contributor.authorSchibille, Nadine
dc.contributor.authorPradell, Trinitat
dc.contributor.authorCastillejo, Marta
dc.contributor.authorOujja, Mohamed
dc.contributor.authorPalomar, Teresa
dc.contributor.institutionVICARTE - Vidro e Cerâmica para as Artes
dc.contributor.pblWiley
dc.date.accessioned2025-07-09T21:16:37Z
dc.date.available2025-07-09T21:16:37Z
dc.date.issued2025-02-03
dc.descriptionFunding Information: This research has been funded by the Fundação de Ciência e Tecnologia from Portugal (project ref. UIDB/EAT/00729/2020, UIDP/00729/2020, 2023.05135.RESTART, and researcher grant CEECIND/02249/2021), the Spanish State Research Agency (AEI) through the projects PID2022-137017OB-I00/AEI/1013039/501100011033 and PID2022-137783OB-I00, the Regional Government of Madrid through the project TEC Heritage-CM (TEC-2024/TEC-39), the Generalitat de Catalunya through the Consolidated Group 2021 SGR 00343, support from CSIC Platform ′Open Heritage: Research and Society′ (PTI-PAIS) and the CSIC Open Access Publication Support Initiative through its Unit of Information Resources for Research (URICI) are acknowledged. Teresa Palomar thanks MICIU for Ramón y Cajal contract (RYC2023-045699-I). Publisher Copyright: © 2025 The Author(s). Chemistry - Methods published by Chemistry Europe and Wiley-VCH GmbH.
dc.description.abstractStained-glass windows are often painted with grisailles and enamels. These glassy materials have a low melting temperature and are fixed to the base glass by firing processes. Lead and/or boron are commonly added to the painting material to lower their melting temperature so that they can melt without deforming the glass support. In the present study, model glass samples (with well-known boron content), replica and historical materials were analysed for their composition using Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) and Laser Induced Breakdown Spectroscopy (LIBS). The imprint left on the analysed samples after laser irradiation was observed using optical profilometry. The feasibility of using LIBS in situ as a suitable quantitative analytical technique to detect the presence of boron in historical enamels even in very small quantities was assessed. Quantitative information on historical Spanish enamels and grisailles was obtained from calibration curves generated from the model glass samples with known boron content. The proposed procedure enables a satisfactory chemical quantitative study of historical glass materials in situ, regardless of their size, provenance, and chronology.en
dc.description.versionpublishersversion
dc.description.versionpublished
dc.format.extent11
dc.format.extent1968844
dc.identifier.doi10.1002/cmtd.202400057
dc.identifier.issn2628-9725
dc.identifier.otherPURE: 121437529
dc.identifier.otherPURE UUID: d9fea77c-9000-4ae0-8502-0b12013f8a6c
dc.identifier.otherScopus: 85217554625
dc.identifier.otherWOS: 001411915800001
dc.identifier.urihttp://hdl.handle.net/10362/185009
dc.identifier.urlhttps://www.scopus.com/pages/publications/85217554625
dc.identifier.urlhttps://www.webofscience.com/wos/woscc/full-record/WOS:001411915800001
dc.language.isoeng
dc.peerreviewedyes
dc.relationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F00729%2F2020/PT
dc.relationGlass and Ceramic for the Arts
dc.subjectBoron
dc.subjectEnamels
dc.subjectGrisailles
dc.subjectIn-situ Analysis
dc.subjectLaser Ablation Inductively Coupled Plasma Mass Spectrometry
dc.subjectLaser-Induced Breakdown Spectroscopy
dc.subjectElectrochemistry
dc.subjectSpectroscopy
dc.subjectCatalysis
dc.subjectFluid Flow and Transfer Processes
dc.titleDetermination of Boron Content in Surface Paintings From Historical Stained-Glass Windowsen
dc.typejournal article
degois.publication.firstPage1
degois.publication.issue5
degois.publication.lastPage11
degois.publication.titleChemistry-Methods
degois.publication.volume5
dspace.entity.typePublication
oaire.awardNumberUIDP/00729/2020
oaire.awardTitleGlass and Ceramic for the Arts
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F00729%2F2020/PT
oaire.fundingStream6817 - DCRRNI ID
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccess
relation.isProjectOfPublication909f7d71-e69b-4a29-a7f2-875c67c7023b
relation.isProjectOfPublication.latestForDiscovery909f7d71-e69b-4a29-a7f2-875c67c7023b

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