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Printed zinc tin oxide diodes: From combustion synthesis to large-scale manufacturing

2022-03-01Artigo científico Acesso aberto
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dc.contributor.authorCarlos, Emanuel
dc.contributor.authorBranquinho, Rita
dc.contributor.authorJansson, Elina
dc.contributor.authorLeppäniemi, Jaakko
dc.contributor.authorMenezes, José
dc.contributor.authorPereira, Rita
dc.contributor.authorDeuermeier, Jonas
dc.contributor.authorAlastalo, Ari
dc.contributor.authorEiroma, Kim
dc.contributor.authorHakola, Liisa
dc.contributor.authorFortunato, Elvira
dc.contributor.authorMartins, Rodrigo
dc.contributor.institutionUNINOVA-Instituto de Desenvolvimento de Novas Tecnologias
dc.contributor.institutionCENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)
dc.contributor.institutionDCM - Departamento de Ciência dos Materiais
dc.contributor.pblIOP Publishing
dc.date.accessioned2022-03-30T11:55:37Z
dc.date.available2022-07-17T00:31:28Z
dc.date.embargoedUntil2022-07-16
dc.date.issued2022-03-01
dc.description
dc.description.abstractPrinted metal oxide devices have been widely desired in flexible electronic applications to allow direct integration on foils and to reduce electronic waste and associated costs. Especially, semiconductor devices made from non-critical raw materials, such as Zn, Sn (and not, for example, In), have gained significant interest. Despite considerable progress in the field, the upscale requirements from lab to fab scale to produce these materials and devices remain a challenge. In this work, we report the importance of solution combustion synthesis (SCS) when compared with sol-gel in the production of zinc tin oxide (ZTO) thin films using a solvent (1-methoxypropanol) that has lower environmental impact than the widely used and toxic 2-methoxyethanol. To assure the compatibility with low-cost flexible substrates in high-throughput printing techniques, a low annealing temperature of 140 °C was achieved for these thin films by combining SCS and infrared annealing in a short processing time. These conditions allowed the transition from spin-coating (lab scale) to flexographic printing (fab scale) at a printing speed of 10 m min-1 in a roll-to-roll pilot line. The ZTO (1:1 Zn:Sn-ratio) diodes show a rectification ratio of 103, a low operation voltage (≤ 3 V), promising reproducibility and low variability. The results provide the basis for further optimisation (device size, encapsulation) to meet the requirements of diodes in flexible electronics applications such as passive-matrix addressing, energy harvesting and rectification.en
dc.description.versionauthorsversion
dc.description.versionpublishersversion
dc.description.versionpublished
dc.format.extent1702781
dc.format.extent4205479
dc.identifier.doi10.1088/2058-8585/ac4bb1
dc.identifier.issn2058-8585
dc.identifier.otherPURE: 42756605
dc.identifier.otherPURE UUID: 91502066-dd8b-4592-9067-f850eb315e7c
dc.identifier.otherScopus: 85125447697
dc.identifier.otherWOS: 000749511100001
dc.identifier.otherORCID: /0000-0001-9771-8366/work/110591086
dc.identifier.otherORCID: /0000-0002-4202-7047/work/110592261
dc.identifier.otherORCID: /0000-0002-5956-5757/work/110592766
dc.identifier.urihttp://hdl.handle.net/10362/135539
dc.identifier.urlhttps://www.scopus.com/pages/publications/85125447697
dc.language.isoeng
dc.peerreviewedyes
dc.relationinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50025%2F2020/PT
dc.relationInstitute of Nanostructures, Nanomodelling and Nanofabrication
dc.relationFully Oxide-based Zero-Emission and Portable Energy Supply
dc.relationUAVEndure
dc.relationCreativity for Innovation & Growth in Europe
dc.relationMultifunctional Digital Materials Platform for Smart Integrated Applications
dc.relationSYmbiosis for eNERGY harversting concepts for smart platforms on foils
dc.relationinfo:eu-repo/grantAgreement/EC/H2020/787410/EU
dc.relationinfo:eu-repo/grantAgreement/EC/H2020/952169/EU
dc.subjectlow temperature
dc.subjectmetal oxides
dc.subjectprinted Schottky diodes
dc.subjectroll-to-roll (R2R)
dc.subjectsolution combustion synthesis
dc.subjectElectronic, Optical and Magnetic Materials
dc.subjectElectrical and Electronic Engineering
dc.titlePrinted zinc tin oxide diodes: From combustion synthesis to large-scale manufacturingen
dc.typejournal article
degois.publication.issue1
degois.publication.titleFlexible and Printed Electronics
degois.publication.volume7
dspace.entity.typePublication
oaire.awardNumberUIDB/50025/2020
oaire.awardNumber951774
oaire.awardNumber817161
oaire.awardNumber320203
oaire.awardNumber787410
oaire.awardNumber952169
oaire.awardTitleInstitute of Nanostructures, Nanomodelling and Nanofabrication
oaire.awardTitleFully Oxide-based Zero-Emission and Portable Energy Supply
oaire.awardTitleUAVEndure
oaire.awardTitleCreativity for Innovation & Growth in Europe
oaire.awardTitleMultifunctional Digital Materials Platform for Smart Integrated Applications
oaire.awardTitleSYmbiosis for eNERGY harversting concepts for smart platforms on foils
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDB%2F50025%2F2020/PT
oaire.awardURIinfo:eu-repo/grantAgreement/EC/H2020/951774/EU
oaire.awardURIinfo:eu-repo/grantAgreement/EC/H2020/817161/EU
oaire.awardURIinfo:eu-repo/grantAgreement/EC/FP7/320203/EU
oaire.awardURIinfo:eu-repo/grantAgreement/EC/H2020/787410/EU
oaire.awardURIinfo:eu-repo/grantAgreement/EC/H2020/952169/EU
oaire.fundingStream6817 - DCRRNI ID
oaire.fundingStreamH2020
oaire.fundingStreamH2020
oaire.fundingStreamFP7
oaire.fundingStreamH2020
oaire.fundingStreamH2020
project.funder.identifierhttp://doi.org/10.13039/501100001871
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project.funder.identifierhttp://doi.org/10.13039/501100008530
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameEuropean Commission
project.funder.nameEuropean Commission
project.funder.nameEuropean Commission
project.funder.nameEuropean Commission
project.funder.nameEuropean Commission
rcaap.rightsopenAccess
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