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GC-MS and E-Nose Analysis of Office Paper

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Volatile organic compounds (VOCs) emitted from hardwood papers are associated with cellulose fibers, paper fillers, and the manufacturing process used. Volatiles emitted from samples of office (printing and writing) papers from various brands and countries were analyzed by gas chromatography–mass spectrometry (GC-MS) and an electronic nose (e-nose) based on piezoelectric quartz crystals. Dodecanoic acid 1-methylethyl ester (isopropyl dodecanoate) and nonanal have shown to be the dominant compounds in most of the samples analyzed, regardless of the pulpwood used in paper manufacturing: Eucalyptus globulus, acacia, and birch. 3-Hydroxybutanone was detected only in Spanish papers, suggesting it as a potential marker. Additionally, the content in acetic acid enables the identification of recycled paper.

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Publisher Copyright: © 2026 by the authors.

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Electronic nose GC-TOF-MS Office paper Paper wood Piezoelectric quartz crystal Volatile organic compounds Wood fibers Wood pulp Analytical Chemistry Information Systems Atomic and Molecular Physics, and Optics Biochemistry Instrumentation Electrical and Electronic Engineering

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