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Impact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranes

2018-12-01Artigo científico Acesso aberto
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dc.contributor.authorMonteiro, Bernardo
dc.contributor.authorNabais, Ana R.
dc.contributor.authorCasimiro, Maria H.
dc.contributor.authorMartins, Ana P. S.
dc.contributor.authorFrancisco, Rute O.
dc.contributor.authorNeves, Luísa A.
dc.contributor.authorPereira, Cláudia C. L.
dc.contributor.institutionLAQV@REQUIMTE
dc.contributor.institutionDQ - Departamento de Química
dc.contributor.pblMDPI AG
dc.date.accessioned2019-01-25T23:43:26Z
dc.date.available2019-01-25T23:43:26Z
dc.date.issued2018-12-01
dc.descriptionPTDC/CTM-POL/2676/2014 IF/00505/2014 This work was performed under the project "SunStorage-Harvesting and storage of solar energy", with reference POCI-01-0145-FEDER-016387, funded by European Regional Development Fund (ERDF), through COMPETE 2020-Operational Programme for Competitiveness and Internationalization (OPCI), and by national funds, through FCT-Fundacao para a Ciencia e a Tecnologia I.P. This work was supported by the Associated Laboratory for Sustainable Chemistry-Clean Processes and Technologies-LAQV which is financed by national funds from FCT/MEC (UID/QUI/50006/2013) and cofinanced by the ERDF under the PT2020 Partnership Agreement (POCI-01-0145-FEDER-007265) The NMR spectrometers are part of The National NMR Facility, supported by Fundacao para a Ciencia e a Tecnologia (RECI/BBB-BQB/0230/2012). A.R.N. and L.A.N. acknowledge FCT/MCTES for financial support through project PTDC/CTM-POL/2676/2014 and FCT Investigator Contract IF/00505/2014, respectively. C2TN/IST authors gratefully acknowledge the Fundacao para a Ciencia e Tecnologia support through the UID/Multi/04349/2013 project.
dc.description.abstractThe efficient separation of gases has industrial, economic, and environmental importance. Here, we report the improvement in gas separation performance of a polyimide-based matrix (Matrimid®5218) filled with a Cu-based metal organic framework [MOF, Cu3(BTC)2] with two different ionic liquids (ILs) confined within the pores. The chosen ILs are commonly used in gas solubilization, 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIM][BF4]) and 1-Ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIM][OTf]), and the incorporation of the [EMIM][BF4]@Cu-BTC and [EMIM][OTf]@Cu-BTC composites in Matrimid®5218 proved to be an efficient strategy to improve the permeability and selectivity toward CO2/N2 and CO2/CH4 mixtures.en
dc.description.versionpublishersversion
dc.description.versionpublished
dc.format.extent4146483
dc.identifier.doi10.3390/membranes8040093
dc.identifier.issn0076-6356
dc.identifier.otherPURE: 6547862
dc.identifier.otherPURE UUID: b4c9cf60-8e9e-4e80-a287-ff88de05ecc3
dc.identifier.otherScopus: 85055641753
dc.identifier.otherWOS: 000455071400008
dc.identifier.otherPubMed: 30314326
dc.identifier.otherPubMedCentral: PMC6316195
dc.identifier.otherORCID: /0000-0002-9620-6286/work/54824151
dc.identifier.otherORCID: /0000-0003-3421-8676/work/53864269
dc.identifier.urihttp://www.scopus.com/inward/record.url?scp=85055641753&partnerID=8YFLogxK
dc.identifier.urlhttps://www.scopus.com/pages/publications/85055641753
dc.language.isoeng
dc.peerreviewedyes
dc.relationinfo:eu-repo/grantAgreement/FCT/5876/147218/PT
dc.relationinfo:eu-repo/grantAgreement/FCT/3599-PPCDT/127013/PT
dc.relationNMR Net - National Facility for Nuclear Magnetic Resonance: from Molecular Structure and Dynamics to Protein Function, Cell Physiology, and Metabolomics
dc.subjectCu(BTC)2
dc.subjectGas separation
dc.subjectIL@Cu(BTC)2
dc.subjectIL@MOF
dc.subjectIonic liquids
dc.subjectMetal-organic frameworks
dc.subjectMixed matrix membranes
dc.subjectChemical Engineering (miscellaneous)
dc.subjectProcess Chemistry and Technology
dc.subjectFiltration and Separation
dc.titleImpact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranesen
dc.typejournal article
degois.publication.issue4
degois.publication.titleMembranes
degois.publication.volume8
dspace.entity.typePublication
oaire.awardNumberUID/QUI/50006/2013
oaire.awardNumberRECI/BBB-BQB/0230/2012
oaire.awardNumberUID/Multi/04349/2013
oaire.awardTitleNMR Net - National Facility for Nuclear Magnetic Resonance: from Molecular Structure and Dynamics to Protein Function, Cell Physiology, and Metabolomics
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876/UID%2FQUI%2F50006%2F2013/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/3599-PPCDT/RECI%2FBBB-BQB%2F0230%2F2012/PT
oaire.awardURIinfo:eu-repo/grantAgreement/FCT/5876/UID%2FMulti%2F04349%2F2013/PT
oaire.fundingStream5876
oaire.fundingStream3599-PPCDT
oaire.fundingStream5876
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.identifierhttp://doi.org/10.13039/501100001871
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
project.funder.nameFundação para a Ciência e a Tecnologia
rcaap.rightsopenAccess
relation.isProjectOfPublicationb46f8ec0-8992-489c-89d9-54c4a065dc4a
relation.isProjectOfPublication496a7d06-5c0c-454e-b230-6c18802762f6
relation.isProjectOfPublication80fb915e-5f41-47de-bcc8-2ac183bb4a79
relation.isProjectOfPublication.latestForDiscovery496a7d06-5c0c-454e-b230-6c18802762f6

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