Publicação
Impact of the Cationic Moiety of Ionic Liquids on Chemoselective Artificial Olfaction
| dc.contributor.author | Oliveira, Ana Rita | |
| dc.contributor.author | Ramou, Efthymia | |
| dc.contributor.author | Palma, Susana I. C. J. | |
| dc.contributor.author | Esteves, Carina | |
| dc.contributor.author | Barbosa, Arménio | |
| dc.contributor.author | Roque, Ana Cecília Afonso | |
| dc.contributor.institution | UCIBIO - Applied Molecular Biosciences Unit | |
| dc.contributor.institution | DQ - Departamento de Química | |
| dc.contributor.pbl | ACS - American Chemical Society | |
| dc.date.accessioned | 2023-09-18T22:13:52Z | |
| dc.date.available | 2023-09-18T22:13:52Z | |
| dc.date.issued | 2023-11-08 | |
| dc.description | Funding Information: This research was funded by the European Research Council (ERC) under the EU Horizon 2020 research and innovation program [grant reference SCENT-ERC-2014-STG-639123, 2015–2022, and Grant Agreement No. 101069405─ENSURE─ERC-2022-POC1]. Publisher Copyright: © 2023 The Authors. Published by American Chemical Society. | |
| dc.description.abstract | Ionogels and derived materials are assemblies of polymers and ionic liquids characterized by high stability and ionic conductivity, making them interesting choices as gas sensors. In this work, we assessed the effect of the ionic liquid moiety to generate ionogels and hybrid gels as electrical and optical gas sensors. Six ionic liquids consisting of a constant anion (chloride) and distinct cationic head groups were used to generate ionogels and hybrid gels and further tested as gas sensors in customized electronic nose devices. In general, ionogel-based sensors yielded higher classification accuracies of standard volatile organic compounds when compared to hybrid material-based sensors. In addition, the high chemical diversity of ionic liquids is further translated to a high functional diversity in analyte molecular recognition and sensing. | en |
| dc.description.version | publishersversion | |
| dc.description.version | published | |
| dc.format.extent | 9 | |
| dc.format.extent | 6101697 | |
| dc.identifier.doi | 10.1021/acsmaterialsau.3c00042 | |
| dc.identifier.issn | 2694-2461 | |
| dc.identifier.other | PURE: 71845945 | |
| dc.identifier.other | PURE UUID: 76df3550-534c-498e-84cc-d8b400fc0e1c | |
| dc.identifier.other | Scopus: 85169336694 | |
| dc.identifier.other | WOS: 001048431900001 | |
| dc.identifier.other | ORCID: /0000-0002-1851-8110/work/151391299 | |
| dc.identifier.other | ORCID: /0000-0002-9756-4958/work/151404427 | |
| dc.identifier.uri | http://hdl.handle.net/10362/157968 | |
| dc.identifier.url | https://www.scopus.com/pages/publications/85169336694 | |
| dc.language.iso | eng | |
| dc.peerreviewed | yes | |
| dc.relation | info:eu-repo/grantAgreement/FCT/9471 - RIDTI/PTDC%2FBII-BIO%2F28878%2F2017/PT | |
| dc.relation | Bio-inspired materials for fish spoilage control | |
| dc.relation | PROTEIOS - Materiais proteicos para sensorização não invasiva | |
| dc.relation | Applied Molecular Biosciences Unit | |
| dc.relation | Applied Molecular Biosciences Unit | |
| dc.relation | Institute for Health and Bioeconomy | |
| dc.relation | An affinity-based approach towards highly specific odor sensing | |
| dc.relation | info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/LA%2FP%2F0140%2F2020/PT | |
| dc.relation | info:eu-repo/grantAgreement/FCT/OE/SFRH%2FBD%2F128687%2F2017/PT | |
| dc.subject | electronic nose | |
| dc.subject | gas sensing | |
| dc.subject | hybrid gels | |
| dc.subject | ionic liquids | |
| dc.subject | ionogels | |
| dc.subject | Electronic, Optical and Magnetic Materials | |
| dc.subject | Biomaterials | |
| dc.subject | Polymers and Plastics | |
| dc.subject | Materials Chemistry | |
| dc.title | Impact of the Cationic Moiety of Ionic Liquids on Chemoselective Artificial Olfaction | en |
| dc.type | journal article | |
| degois.publication.firstPage | ||
| degois.publication.lastPage | ||
| degois.publication.title | ACS Materials Au | |
| degois.publication.volume | 3 | |
| dspace.entity.type | Publication | |
| oaire.awardNumber | PTDC/BII-BIO/28878/2017 | |
| oaire.awardNumber | PTDC/CTM-CTM/3389/2021 | |
| oaire.awardNumber | UIDP/04378/2020 | |
| oaire.awardNumber | UIDB/04378/2020 | |
| oaire.awardNumber | LA/P/0140/2020 | |
| oaire.awardNumber | SFRH/BD/128687/2017 | |
| oaire.awardTitle | Bio-inspired materials for fish spoilage control | |
| oaire.awardTitle | PROTEIOS - Materiais proteicos para sensorização não invasiva | |
| oaire.awardTitle | Applied Molecular Biosciences Unit | |
| oaire.awardTitle | Applied Molecular Biosciences Unit | |
| oaire.awardTitle | Institute for Health and Bioeconomy | |
| oaire.awardTitle | An affinity-based approach towards highly specific odor sensing | |
| oaire.awardURI | info:eu-repo/grantAgreement/FCT/9471 - RIDTI/PTDC%2FBII-BIO%2F28878%2F2017/PT | |
| oaire.awardURI | info:eu-repo/grantAgreement/FCT/Concurso de Projetos IC&DT em Todos os Domínios Científicos/PTDC%2FCTM-CTM%2F3389%2F2021/PT | |
| oaire.awardURI | info:eu-repo/grantAgreement/FCT/6817 - DCRRNI ID/UIDP%2F04378%2F2020/PT | |
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| oaire.awardURI | info:eu-repo/grantAgreement/FCT//SFRH%2FBD%2F128687%2F2017/PT | |
| oaire.fundingStream | 9471 - RIDTI | |
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| project.funder.name | Fundação para a Ciência e a Tecnologia | |
| project.funder.name | Fundação para a Ciência e a Tecnologia | |
| project.funder.name | Fundação para a Ciência e a Tecnologia | |
| project.funder.name | Fundação para a Ciência e a Tecnologia | |
| project.funder.name | Fundação para a Ciência e a Tecnologia | |
| project.funder.name | Fundação para a Ciência e a Tecnologia | |
| rcaap.rights | openAccess | |
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