Carbon Dioxide Utilisation -The Formate Route

Maia, Luisa; Moura, Isabel; Moura, José J. G.

Publicação

Carbon Dioxide Utilisation -The Formate Route

2021Capítulo de livro

dc.contributor.author	Maia, Luisa
dc.contributor.author	Moura, Isabel
dc.contributor.author	Moura, José J. G.
dc.contributor.institution	LAQV@REQUIMTE
dc.coverage.spatial	Cham
dc.date.accessioned	2021-01-05T23:15:08Z
dc.date.available	2021-01-05T23:15:08Z
dc.date.issued	2021
dc.description	UIDB/50006/2020 CEEC-Individual 2017 Program Contract.
dc.description.abstract	The relentless rise of atmospheric CO2 is causing large and unpredictable impacts on the Earth climate, due to the CO2 significant greenhouse effect, besides being responsible for the ocean acidification, with consequent huge impacts in our daily lives and in all forms of life. To stop spiral of destruction, we must actively reduce the CO2 emissions and develop new and more efficient “CO2 sinks”. We should be focused on the opportunities provided by exploiting this novel and huge carbon feedstock to produce de novo fuels and added-value compounds. The conversion of CO2 into formate offers key advantages for carbon recycling, and formate dehydrogenase (FDH) enzymes are at the centre of intense research, due to the “green” advantages the bioconversion can offer, namely substrate and product selectivity and specificity, in reactions run at ambient temperature and pressure and neutral pH. In this chapter, we describe the remarkable recent progress towards efficient and selective FDH-catalysed CO2 reduction to formate. We focus on the enzymes, discussing their structure and mechanism of action. Selected promising studies and successful proof of concepts of FDH-dependent CO2 reduction to formate and beyond are discussed, to highlight the power of FDHs and the challenges this CO2 bioconversion still faces.	en
dc.description.version	publishersversion
dc.description.version	published
dc.format.extent	2317655
dc.identifier.isbn	978-3-030-58314-9
dc.identifier.isbn	978-3-030-58315-6
dc.identifier.other	PURE: 26849217
dc.identifier.other	PURE UUID: 1721ab78-d9d5-438c-afad-79567f98df00
dc.identifier.other	Scopus: 85116478410
dc.identifier.other	ORCID: /0000-0002-4726-2388/work/86284811
dc.identifier.other	ORCID: /0000-0002-6901-6591/work/86285337
dc.identifier.uri	http://hdl.handle.net/10362/109755
dc.identifier.url	https://docentes.fct.unl.pt/lblm/files/co2_utilisation-formatedehydrogenases-maia.pdf
dc.language.iso	eng
dc.peerreviewed	yes
dc.publisher	Springer International Publishing
dc.subject	Carbon dioxide utilisation
dc.subject	Formic acid
dc.subject	Formate dehydrogenase
dc.subject	Molybdenum
dc.subject	Tungsten
dc.subject	Hydride transfer
dc.subject	Biocatalyst
dc.subject	Green chemistry
dc.subject	Energy
dc.subject	Biotechnology
dc.subject	SDG 13 - Climate Action
dc.subject	SDG 14 - Life Below Water
dc.title	Carbon Dioxide Utilisation -The Formate Route	en
dc.type	book part
degois.publication.firstPage	29
degois.publication.lastPage	81
degois.publication.title	Enzymes for Solving Humankind's Problems: Natural and Artificial Systems in Health, Agriculture, Environment and Energy
dspace.entity.type	Publication
rcaap.rights	openAccess

Ficheiros

Principais

A mostrar 1 - 1 de 1

Nome:: CO2_Utilisation_Formate_Formation_2021.pdf
Tamanho:: 2.21 MB
Formato:: Adobe Portable Document Format

Ver/Abrir

Coleções

Home collection (FCT)