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Colour modulation of blue anthocyanin-derivatives. Lignosulfonates as a tool to improve the water solubility of natural blue dyes
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Orientador(es)
Resumo(s)
The impact of a lignosulfonate (calcium) (L) on the chromatic features of two anthocyanin-derived bluish dyes (portisin, P and pyranoanthocyanin dimer, PD) was evaluated in aqueous solutions using UV–Visible spectroscopy. It was demonstrated that the interaction between each dye and this macromolecule at pH 1 occurs by two mechanisms, association and copigmentation that are dependent on L concentration. For instance, at low concentrations of L (up to 0.27 μM) it is observed the association of dyes promoted by their complexation with lignin (different molecules of dye are bound to the same binding sites of L). At higher concentrations of L (25 μM), the aggregation of dyes decreases and each molecule is bound to a different site of L resulting in the formation of a charge-transfer complex (copigmentation). Moreover, the titration of both dyes (P and PD) in the presence of L (19 μM) showed a strong stabilization of their pyranoflavylium cation forms revealed by the considerably higher pKa1 (6.6 ± 0.1 and 6.2 ± 0.1 for P and PD, respectively) in the presence of this macromolecule when compared to the values obtained in the absence (pKa1 = 4.61 ± 0.03 and 4.93 ± 0.04). In addition, the water solubility of the dyes in the absence and presence of L was also evaluated by turbidimetry and the results showed that the water soluble lignosulfonate improved the solubility of the dyes over time.
Descrição
SFRH/BPD/112465/2015
IF/00225/2015
PTDC/AGR-TEC/2789/2014
COMPETE POCI-01-0145-FEDER-016616
REDE/1517/RMN/2005
PT2020 and FEDER-Interreg Espana-Portugal Programme (Project ref. 0377_IBERPHENOL_6_E).
Palavras-chave
Aggregation Calcium lignosulfonate Charge-transfer complex Colour Portisins Pyranoanthocyanin dimers General Chemical Engineering Process Chemistry and Technology