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Projeto de investigação
Cellulose based Bio-foam for Interactive Energy Harvester
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Sustainable electrochemical energy storage devices using natural bast fibres
Publication . Manjakkal, Libu; Jain, Amrita; Nandy, Suman; Goswami, Sumita; Tiago Carvalho, José; Pereira, Luís; See, Chan H.; Pillai, Suresh C.; Hogg, Richard A.; UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias; DCM - Departamento de Ciência dos Materiais; CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N); Elsevier Science Publisher B.V.
Naturally abundant materials play a crucial role in the development of sustainable electrochemical energy storage (EES) devices including batteries and supercapacitors (SCs). This is due to limited available resources with regards to energy storage materials, and the environmental pollution produced by the toxic materials utilized in conventional EESs. In the current review, development in the field of natural bast fibres (jute, flax, hemp and kenaf) based EES devices performances is highlighted. This review emphasizes methods such as the direct use of modified fibres and activated carbon from biomass for the design of EES devices. Activated fibres were developed using both physical and chemical activation methods. Key challenges including active electrode materials preparation, capacitive retention, and the implementation of the fibre based EES devices are critically discussed. Furthermore, the recent surge in the use of wearables and portable technologies that demand further development of flexible/non-flexible EES devices are also explored. Future trends and perspectives on materials development, power management interface, recycling, biodegradability and circular economy are also addressed. It is concluded that the development of new renewable energy systems using bast fibres has many remarkable advances in device performance. For this, an innovative approach is required to develop high energy density bast fibre based sustainable EES devices which will be potentially implemented for clean energy solutions.
Energy harvesting and movement tracking by polypyrrole functionalized textile for wearable IoT applications
Publication . Ferreira, Guilherme; Das, Shubham; Coelho, Guilherme; Silva, Rafael R. A.; Goswami, Sumita; Pereira, Rui N.; Pereira, Luís; Fortunato, Elvira; Martins, Rodrigo; Nandy, Suman; DCM - Departamento de Ciência dos Materiais; CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N); UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias; Elsevier BV
Textiles for health and sporting activity monitoring are on the rise with the advent of smart portable wearables. The intention of this work is to design wireless monitoring wearables, based on widely available textiles and low environmental impact production technologies. Herein we have developed a polymeric ink which is able to functionalize different types of textile fibers (including silver conducting fibers, cotton, and commercial textile) with polypyrrole. These fibers were weaved together with a thinner silver conducting fiber and carbon fiber to form a touch-sensitive energy harvesting system that would generate an electric output when mechanical pressure is applied to it. Different prototypes were manufactured with loom weaving accessories to simulate real textile cloths. By simple touch, the prototypes produced a maximum voltage of 244 V and a maximum power density of 2.29 W m−2. The current generated is then transformed into a digital signal, which is further utilized for human motion or gesture monitorization. The system comprises a wireless block for the Internet of Things (IoT) applicability that will be eventually extended to future remote health and sports monitoring systems.
Polyaniline and its composites engineering
Publication . Goswami, Sumita; Nandy, Suman; Fortunato, Elvira; Martins, Rodrigo; UNINOVA-Instituto de Desenvolvimento de Novas Tecnologias; DCM - Departamento de Ciência dos Materiais; CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N); Academic Press Inc.
Polymer material provides significant advantages over the conventional inorganic material-based electronics due to its attractive features including miniaturized dimension and feasible improvisations in physical properties through molecular design and chemical synthesis. In particular, conjugate polymers are of great interest because of their ability to control the energy gap and electronegativity through molecular design that has made possible the synthesis of conducting polymers with a range of ionization potentials and electron affinities. Polyaniline (PANI) is one of the most popular conjugated polymers that has been widely explored so far for its multifunctionality in diverse potential applications. This review is focusing on the recent advances of PANI for smart energy applications including supercapacitors, batteries, solar cells and nanogenerators and the development in its synthesis, design, and fabrication processes. A details investigation on the different types of chemical process has been discussed to fabricate PANI in nanostructures, film, and composites form. The paper includes several studies which are advantageous for understanding: the unique chemical and physical properties of this polymer; and the easily tunable electrical properties along with its redox behavior; and different processes to develop nanostructures, film, or bulk form of PANI that are useful to derive its applicability in smart objects or devices.
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Entidade financiadora
Fundação para a Ciência e a Tecnologia
Programa de financiamento
3599-PPCDT
Número da atribuição
M-ERA-NET3/0004/2021