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  3. Faculdade de Ciências e Tecnologia (FCT)
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  5. FCT: Departamento de Química
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Utilize este identificador para referenciar este registo: http://hdl.handle.net/10362/58658
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Campo DCValorIdioma
dc.contributor.authorMonteiro, Bernardo-
dc.contributor.authorNabais, Ana R.-
dc.contributor.authorCasimiro, Maria H.-
dc.contributor.authorMartins, Ana P. S.-
dc.contributor.authorFrancisco, Rute O.-
dc.contributor.authorNeves, Luísa A.-
dc.contributor.authorPereira, Cláudia C. L.-
dc.date.accessioned2019-01-25T23:43:26Z-
dc.date.available2019-01-25T23:43:26Z-
dc.date.issued2018-12-01-
dc.identifier.citationMonteiro, B., Nabais, A. R., Casimiro, M. H., Martins, A. P. S., Francisco, R. O., Neves, L. A., & Pereira, C. C. L. (2018). Impact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranes. Membranes, 8(4), Article 93. https://doi.org/10.3390/membranes8040093-
dc.identifier.issn0076-6356-
dc.identifier.otherPURE: 6547862-
dc.identifier.otherPURE UUID: b4c9cf60-8e9e-4e80-a287-ff88de05ecc3-
dc.identifier.otherScopus: 85055641753-
dc.identifier.otherWOS: 000455071400008-
dc.identifier.otherPubMed: 30314326-
dc.identifier.otherPubMedCentral: PMC6316195-
dc.identifier.otherORCID: /0000-0002-9620-6286/work/54824151-
dc.identifier.otherORCID: /0000-0003-3421-8676/work/53864269-
dc.identifier.urihttp://www.scopus.com/inward/record.url?scp=85055641753&partnerID=8YFLogxK-
dc.descriptionPTDC/CTM-POL/2676/2014 IF/00505/2014 This work was performed under the project "SunStorage-Harvesting and storage of solar energy", with reference POCI-01-0145-FEDER-016387, funded by European Regional Development Fund (ERDF), through COMPETE 2020-Operational Programme for Competitiveness and Internationalization (OPCI), and by national funds, through FCT-Fundacao para a Ciencia e a Tecnologia I.P. This work was supported by the Associated Laboratory for Sustainable Chemistry-Clean Processes and Technologies-LAQV which is financed by national funds from FCT/MEC (UID/QUI/50006/2013) and cofinanced by the ERDF under the PT2020 Partnership Agreement (POCI-01-0145-FEDER-007265) The NMR spectrometers are part of The National NMR Facility, supported by Fundacao para a Ciencia e a Tecnologia (RECI/BBB-BQB/0230/2012). A.R.N. and L.A.N. acknowledge FCT/MCTES for financial support through project PTDC/CTM-POL/2676/2014 and FCT Investigator Contract IF/00505/2014, respectively. C2TN/IST authors gratefully acknowledge the Fundacao para a Ciencia e Tecnologia support through the UID/Multi/04349/2013 project.-
dc.description.abstractThe efficient separation of gases has industrial, economic, and environmental importance. Here, we report the improvement in gas separation performance of a polyimide-based matrix (Matrimid®5218) filled with a Cu-based metal organic framework [MOF, Cu3(BTC)2] with two different ionic liquids (ILs) confined within the pores. The chosen ILs are commonly used in gas solubilization, 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIM][BF4]) and 1-Ethyl-3-methylimidazolium trifluoromethanesulfonate ([EMIM][OTf]), and the incorporation of the [EMIM][BF4]@Cu-BTC and [EMIM][OTf]@Cu-BTC composites in Matrimid®5218 proved to be an efficient strategy to improve the permeability and selectivity toward CO2/N2 and CO2/CH4 mixtures.en
dc.language.isoeng-
dc.relationinfo:eu-repo/grantAgreement/FCT/5876/UID%2FQUI%2F50006%2F2013/PT-
dc.relationinfo:eu-repo/grantAgreement/FCT/3599-PPCDT/RECI%2FBBB-BQB%2F0230%2F2012/PT-
dc.relationinfo:eu-repo/grantAgreement/FCT/5876/UID%2FMulti%2F04349%2F2013/PT-
dc.rightsopenAccess-
dc.subjectCu(BTC)2-
dc.subjectGas separation-
dc.subjectIL@Cu(BTC)2-
dc.subjectIL@MOF-
dc.subjectIonic liquids-
dc.subjectMetal-organic frameworks-
dc.subjectMixed matrix membranes-
dc.subjectChemical Engineering (miscellaneous)-
dc.subjectProcess Chemistry and Technology-
dc.subjectFiltration and Separation-
dc.titleImpact on CO2/N2 and CO2/CH4 separation performance using Cu-BTC with supported ionic liquids-based mixed matrix membranes-
dc.typearticle-
degois.publication.issue4-
degois.publication.titleMembranes-
degois.publication.volume8-
dc.peerreviewedyes-
dc.identifier.doihttps://doi.org/10.3390/membranes8040093-
dc.description.versionpublishersversion-
dc.description.versionpublished-
dc.contributor.institutionLAQV@REQUIMTE-
dc.contributor.institutionDQ - Departamento de Química-
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