Utilize este identificador para referenciar este registo: http://hdl.handle.net/10362/146556
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dc.contributor.authorRossignon, Alexandre-
dc.contributor.authorBerna, Beatrice Berionni-
dc.contributor.authorParola, A. Jorge-
dc.contributor.authorLaia, César A. T.-
dc.contributor.authorBonifazi, Davide-
dc.date.accessioned2022-12-22T22:18:50Z-
dc.date.available2022-12-22T22:18:50Z-
dc.date.issued2022-12-
dc.identifier.otherPURE: 48434137-
dc.identifier.otherPURE UUID: b140c5fb-2d19-4310-8f45-ab12dd46988c-
dc.identifier.otherORCID: /0000-0002-1333-9076/work/124651316-
dc.identifier.otherORCID: /0000-0001-6410-6072/work/125202862-
dc.identifier.otherScopus: 85165666866-
dc.identifier.urihttp://hdl.handle.net/10362/146556-
dc.descriptionFunding Information D.B. gratefully acknowledges the EU through the MSCA-RISE (project: INFUSION, No. 734834) and MSCA-IF “ENTERPRISE” (project number: 897396) and the University of Vienna for generous financial support. B.B.B. thanks the MSCA-IF “ENTERPRISE” project for her post-doctoral fellowship. A.R. thanks the FNRS for his doctoral fellowship. The collaboration between D.B., J.P. and C.L. is supported by the MSCA-RISE INFUSION project.-
dc.description.abstractA series of novel O-doped polycyclic aromatic hydrocarbons (PAHs), bearing a different number of electron donating alkoxy substituents, has been prepared using a novel copper-promoted anaerobic protocol for the cyclisation of highly electron rich peri-xanthenoxanthene (PXX) molecular modules. The effect of the number and position of the alkoxy substituents on the optoelectronic properties has thus been investigated, unveiling p-type semiconducting properties. All molecules displayed a significant colour change upon oxidation, suggesting that these compounds can be used to devise chromogenic materials to engineer electrochromic devices.en
dc.format.extent14-
dc.language.isoeng-
dc.rightsopenAccess-
dc.subjectPolycyclic aromatic hydrocarbons-
dc.subjectPXX-
dc.subjectElectrochromism-
dc.subjectOxygen heterocycles-
dc.subjectElectrochromic devices-
dc.titleHOMO Energy-Level Lifting in p-Type O-Doped Graphenoids-
dc.typearticle-
degois.publication.firstPage241-
degois.publication.lastPage254-
degois.publication.titleOrganic Materials-
degois.publication.volume4-
dc.peerreviewedyes-
dc.identifier.doihttps://doi.org/10.1055/a-1976-0291-
dc.description.versionpublishersversion-
dc.description.versionpublished-
dc.title.subtitleSynthesis of Electrochromic Alkoxy-Decorated Xanthenoxanthenes-
dc.contributor.institutionDQ - Departamento de Química-
dc.contributor.institutionLAQV@REQUIMTE-
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