Paulino, Graziela dos SantosPereira, Júlia SantosMarques, Clara SupraniVitalino, Kyssila Vitória ReisSouza, Victor G. L.Aguilar, Ananda PereiraAlmeida, Lucas Filipede Oliveira, Taíla VelosoRibon, Andréa de Oliveira BarrosFerreira, Sukarno OlavoMoura, Eveline Teixeira CaixetaSilva, Deusanilde de JesusMendes, Tiago Antônio de Oliveira2026-02-122026-02-122025-12-182079-9276PURE: 152910084PURE UUID: 18b55525-2c6e-413b-8fa6-1b775f508638Scopus: 105025759960WOS: 001648661900001http://hdl.handle.net/10362/200314Publisher Copyright: © 2025 by the authors.Most polymeric plastics used as food packaging are obtained from petroleum or made with non-biodegradable synthetic molecules, which slowly degrade and leach into the environment, resulting in the accumulation of microplastics along the trophic chains. To mitigate these impacts, biodegradable packaging derived from agro-industrial biomass residues has emerged as a promising alternative. In this study, bio-based methylcellulose films reinforced with cellulose nanocrystals (CNCs) extracted from low-quality coffee beans were developed and fully characterized. The extracted CNCs presented a needle-like morphology, with an average height of 7.27 nm and a length of 221.34 nm, with 65.75% crystallinity, were stable at pH 7–8, and presented thermogravimetric mass loss of 8.0%. Methylcellulose films containing 0.6% w/w of CNC were produced by casting and characterized in terms of thermal, mechanical, and optical properties. Notably, the incorporation of CNCs resulted in significantly more flexible and less rigid films, as evidenced by the higher elongation at break (57.90%) and lower Young’s modulus (0.0015 GPa) compared to neat methylcellulose film. The tensile strength was not affected (p > 0.05). Additionally, the MCNC 0.6% films effectively blocked UV light in the 200–300 nm range without compromising transparency. Altogether, these findings underscore the MCNC 0.6% film as a flexible, biodegradable packaging material suitable for food industry application.243584657engAcid hydrolysisAgro-industrial wasteBioplasticsCrystallinityMethylcelluloseNature and Landscape ConservationManagement, Monitoring, Policy and Lawjournal article10.3390/resources14120191https://www.scopus.com/pages/publications/105025759960https://www.webofscience.com/wos/woscc/full-record/WOS:001648661900001